Research Results For 'Manganese'

CAPPAGH BROWN

Cappagh brown is a bituminous earth, coloured by oxide of manganese and iron, which yields pigments of various rich brown colours. It is called also manganese brown andt derives its name from Cappagh, near Cork, in Ireland.
Research Cappagh Brown

DYEING

Dyeing is the art of giving colour to textile and other articles in such a way that the colours are more or less permanent, and not readily affected by the action of light, washing, etc. Like spinning and weaving it was originally a home industry, as it still is in many places. Until about 1850 natural dye-stuffs alone were employed, but the discovery of dyes of all colours that can be obtained from coal-tar products revolutionized dyeing as an industry, and the vegetable dye-stuffs were gradually superseded by the newer colours.

Before dyeing, the materials have generally to be cleansed or bleached to get rid of undesirable colouring matters or impurities; and frequently a textile material is subjected to some subsidiary treatment in order to obtain special effects. For example, cotton yarn may be subjected to the action of strong caustic soda ('mercerizing' process) while in a state of great tension, in order to give it a permanent silky lustre.

Dyeing is not only an art, it is also a branch of applied chemistry. One fundamental principle is, that the colouring matter and other necessary substances must be applied in a state of solution, and while in direct contact with the fibre they must be rendered insoluble, so that they are precipitated within or upon the fibre and thus permanently fixed. The method of effecting this varies greatly according to the fibre and the colouring matter employed. As a rule the vegetable and the animal fibres are dyed by very different methods. The affinity of the animal fibres for certain colouring matters is often so great that they are readily dyed by simple immersion in hot colour solutions;
but this simple process is not generally sufficient. According to the method of their application in dyeing the following groups: of dye-stuffs may be distinguished: Avid Colours, Basic Colours, Direct Colours, Developed Colours, Mordant Colours, Miscellaneous Colours, Reactive Colours.

The acid colours are so called because they are of an acid character and are applied in an acid dye-bath. As a rule, they are only suitable for dyeing the animal fibres, e.g. wool and silk, also leather, horn, feathers, etc. Only a few vegetable dye-stuffs belong to this class, for example, the purple colour orchil and the blue colour indigo extract. On the other hand, the acid colours derived from coal-tar - and increasingly petroleum - are very numerous and yield a great variety of hues - red, orange, yellow, green, blue, violet, brown, and black, each with its particular name.

The basic colours are so called because their essential constituents, to which they owe their dyeing power, are organic bases. The bases themselves are colourless and too insoluble in water to be of use, hence they are employed in the form of their soluble coloured salts, usually the hydrochlorides of the colour-bases. Their solutions are precipitated by tannic acid, because it combines with the colour-bases to form insoluble tannates. Wool, silk, and animal substances generally have a direct attraction for colour-bases, and hence these fibres are readily dyed by simple immersion in hot aqueous solutions of the basic colours. Cotton and linen, on the other hand, are not dyed so readily; they need first to be prepared or impregnated with tannic acid, and thus prepared are said to be mordanted, the tannic acid in this connection being styled the mordant. Most of the colours of this class are fugitive to light, and all but one, barberry root, are derived from coal-tar products.

The direct colours are so called because they dye cotton direct, that is, without the aid of any mordanting process. The first of this class derived from coal-tar was congo red, discovered in 1884; this group includes a very great variety of fast colours, and forms, indeed, one of the most important and valuable series of dye-stuffs employed. Cotton, linen, and the vegetable fibres generally are dyed in the simplest possible manner by merely boiling them in a solution of the dye-stuff, with or without the addition of a little soap, carbonate or sulphate of soda, etc. Wool and silk are frequently dyed in the same manner as cotton. Very few vegetable dye-stuffs belong to the direct colours, e.g. Safflower, Turmeric, Saffron, Annatto. They are all fugitive, and have been of little or no importance to the dyer since the end of the 19th century. The coal-tar colours of this class, on the other hand, are extremely numerous.

The developed colours include a variety of colours which are formed in situ upon the fibre by the successive application of two or more substances. These colours are all of coal-tar origin. A number of them belong to the so-called azo colours, derived from compounds containing nitrogen.

The mordant colours form one of the most important classes of colouring matters, for they include not only most of the vegetable dye-stuffs, e.g. madder, logwood, fustic, etc, but also many valuable fast coal-tar colours, commonly known as the alizarin colours, after their typical representative, alizarin. These mordant colours have by themselves very little colouring power, as a rule, and if employed alone in dyeing give little or no result. If applied, however, in conjunction with metallic salts, notably those of chromium, aluminium, iron, tin, and copper, they each yield a variety of colours, according to the metallic salt employed. In employing them usually two distinct operations are involved: first, that of applying the metallic salt or mordant, called the mordanting process ; and second, that of dyeing proper, in which the mordanted material is boiled in a solution or decoction of the dye-stuff. During the dyeing operation the colouring principle of the dye-stuff combines with the metallic salt already upon the material, and the colour is thus produced and fixed upon the fibre. The method of mordanting varies with the fibre and the metallic salt employed. The vegetable dye-stuffs of this class include Madder, Sapanwood, Camwood, Barwood, Old Fustic, Young Fustic, Quercitron Bark, Persian Berries, Weld, Logwood. Madder was formerly the most important and highly valued of the dye-stuffs of this class, being especially employed to produce the fine 'Turkey-red' dye; but was entirely superseded by the coal-tar colour alizarin towards the end of the 19th century.

Reactive colours combine directly with the fibre being dyed through a chemical reaction and result in a fast colour. The first ranges of reactive dyes for cellulose fibres were introduced in the mid-1950s.

Similarly, the employment of cochineal (an insect dye) has also greatly diminished through the introduction of the cheaper colours. Camwood and barwood are almost entirely used in wool-dyeing, either in conjunction with the indigo-vat or for the purpose of dyeing various shades of brown. Old fustic is the most important of the yellow mordant dye-stuffs, and the colours are fast although not very brilliant. Young fustic yields fugitive colours, and has been little used since 1900. Quercitron bark is an excellent dye-stuff employed by wool-dyers for the production of bright orange and yellow colours. Persian berries and weld, a species of wild mignonette, are both excellent dye-stuffs, but their employment is now limited. Logwood is largely employed by wool, silk, and cotton dyers for dyeing black and dark-blues, which, although fast to washing, are only moderately so towards light. During the 20th century dyewoods were gradually replaced by coal-tar colours.

Among miscellaneous colours are several dye-stuffs applied in a distinct manner. Indigo is a dark-blue powder quite insoluble in water, but can be rendered soluble for dyeing purposes by two methods. The first method converts the indigo into so-called indigo extract, which is sold as a blue paste and applied as an acid colour in dyeing wool and silk. In the second method the indigo-blue is converted into indigo-white, which readily dissolves in the alkali present, the solution thus obtained being called an indigo-vat. If cotton, wool, or silk is steeped for some time in the clear yellow solution of such a vat, and then exposed to the oxidizing influence of the air, they are dyed a permanent blue. The indigo-white absorbed by the fibre loses its acquired hydrogen, and thus insoluble indigo-blue is regenerated within and upon the fibre. Aniline black is a valuable colour, produced direct upon the fibre by the oxidation of aniline, and remarkable for its extreme permanency.

Catechu is a vegetable dye-stuff used in dyeing cotton and woollen brown. On wool, catechu yields khaki browns in single bath by using copper sulphate as the mordant. On silk it is largely employed for weighting purposes in the process of dyeing black. Chrome Yellow, Iron Buff, Prussian Blue, and Manganese Brown, employed in cotton dyeing, are frequently classed as mineral colours. Chrome yellow is obtained by immersing cotton successively in solutions of acetate of lead and bichromate of potash, whereby the yellow precipitate of chromate of lead is fixed upon the fibre. Iron buff is obtained in a similar manner by the successive application of iron sulphate and carbonate of soda, and finally developing the full colour by washing with water and exposure to air. The buff colour is really due to the precipitation of oxide of iron on the cotton. Prussian blue is at once developed by passing the buff-dyed cotton through an acidified solution of potassium ferrocyanide. The production of manganese brown on cotton is similar to that of iron buff. The brown colour ultimately produced upon the fibre is an oxide of manganese. The mineral colours are very useful for certain purposes, and are to be regarded as very fast to light.
Research Dyeing

ENAMEL

Enamel is a vitreous glaze of various colours fused to the surface of gold, silver, copper, and other substances. The art of enamelling, which is of great antiquity, was practised by the Assyrians and by the Egyptians, from whom it may have passed into Greece, and thence into Rome and its provinces, including Great Britain, where various Roman antiquities with enamelled ornamentation have been discovered. The enamelled gold cup given by King John to the corporation of Lynn, in Norfolk, proves that the art was known among the Normans. The Byzantines of the 10th century produced excellent cloisonne enamels on a gold base, the cloisonne process consisting in tracing the design in fillets of gold upon the gold plate and filling up the small moulds thus formed with enamels the design appearing in coloured enamels separated by thin gold partitions or cloisons. In some cases, however, the enamels were filled into hollows beaten out in the gold plate, which formed part of the field.

In the 12th century the town of Limoges acquired the high reputation for inlaid enamels which it held until the 14th century, aud re-acquired in the 16th for its painted enamels. The costliness of the sculptured ground had led the Italians early in the 14th century to substitute the practice of incising the design on the face of the plate, and then covering it with a transparent enamel. The further step, which made the Limousin workshops famous, consisted in the method of superficial enamelling, in which opaque colours or colours laid on a white opaque ground were used. The Limoges school degenerated greatly in the 17th century, but its method with certain modifications in detail is still employed.

The basis of all kinds of enamel is a perfectly transparent and fusible glass, which is rendered either semitransparent or opaque by the admixture of metallic oxides. White enamels are composed by melting the oxide of tin with glass, and adding a small quantity of manganese or phosphate of calcium to increase the brilliancy of the colour. The addition of the oxide of lead, or antimony, or oxide of silver, produces a yellow enamel. Reds are formed by copper, and by an intermixture of the oxides of gold and iron. Greens, violets, and blues are formed from the oxides of copper, cobalt, and iron.

In the middle of the 18th century enamelling was largely applied to the decoration of snuff-boxes, tea-canisters, candlesticks, and other small articles. Of later years it was extensively applied to the coating of iron vessels for domestic purposes, the protection of the insides of baths, cisterns, and boilers, and the like. Enamelling in colours upon iron was common, iron plates being thus treated by means of various mixtures, and words and designs of various kinds being permanently fixed upon them by stencilling, for advertising, signboards, etc.

PLATEAU

A plateau or tableland generally denotes a large stretch of highland which is practically the same height above sea-level, and which descends on all sides to lower ground. Some plateaux, however, such as those of Tibet and Bolivia, that are fringed by high mountain ranges which tower above the plateau level, are known as intermont plateaux. Sometimes they are so completely enclosed as to have no outlet to the sea.

A plateau might be regarded as an elevated plain, but there is often a great difference between the surface of a plain and that of a plateau. As a plateau is high, rivers are swift and carve deep, narrow valleys instead of the broad, open valleys of the lower rivers of the plains. Such plateau areas as Wales and the Highlands of Scotland, are broken by deep, narrow valleys, and are termed dissected plateaux. On reaching the top of such an area one has a long view of a series of flat-topped mountain ridges. These ridges are all of approximately the same height, and if one imagines the clouds descending until they touched one ridge, then almost every other ridge would be similarly cloud-capped. Other good examples of plateaux are Tibet in Asia, the Ecuador and Bolivian plateaux in South America, and nearly the whole of the continent of Africa.

The Deccan of India is a plateau that has been tilted so that the western edge is much higher than the eastern edge, and all the main rivers drain eastwards. In many instances plateaux are formed by the denudation or wearing down of higher mountainous areas. Ultimately, such areas may become so low that they are nearly plains, i.e. peneplains, such as the land around Hudson Bay. Millions of years ago lava was forced up through cracks in the earth's crust, and spread out over the land in great sheets which have since hardened to form plateaux of basalt.

Two well-known examples of such plateaux are in Antrim (Ireland), and on the Deccan of India to the east of Bombay. Many of the most extensive areas of plateaux in the world are composed of very hard old rock. The Guiana Highlands, most of Africa, Arabia, the Deccan of India, and the West Australian plateaux are all composed of rocks of similar age. The ancient plateau lands are principally valuable for their minerals, such as the gold of Western Australia; the iron and manganese of the Brazilian Highlands; the gold, copper, and diamonds of the African plateau; and the gold of the Lena plateau in Siberia. Where plateaux are found in tropical areas they are important because, being cooler than the neighbouring lowlands, they offer greater possibilities for successful European settlement and development. The highlands of Brazil, Kenya, and Tanganyika are illustrations of this. Much of the tropical plateau area is covered by savannah grasslands. Most of these areas are not yet developed, but offer possibilities for the production of a large variety of both animal and vegetable products when communications have been developed and further settlement has taken place.
Research Plateau

NUTRITION

Nutrition is the strategy adopted by an organism to obtain the chemicals it needs to live, grow, and reproduce. The term is also applied to the science of food, and its effect on human and animal life, health, and disease.
Nutrition involves the study of the basic nutrients required to sustain life, their bio-availability in foods and overall diet, and the effects upon them of cooking and storage. It is also concerned with dietary deficiency diseases. There are six classes of nutrients: water, carbohydrates, proteins, fats, vitamins, and minerals. Water is involved in nearly every body process. Animals and humans will succumb to water deprivation sooner than to starvation. Carbohydrates are composed of carbon, hydrogen and oxygen. The major groups are starches, sugars, and cellulose and related material (or ' roughage'). The prime function of the carbohydrates is to provide energy for the body; they also serve as efficient sources of glucose, which the body requires for brain functioning, utilisation of foods, maintenance of body temperature. Roughage includes the stiff structural materials of vegetables, fruits, and cereal products. Proteins are made up of smaller units, amino acids. The primary function of dietary protein is to provide the amino acids
required for growth and maintenance of body tissues. Both vegetable and animal foods are protein sources. Fats serve as concentrated sources of energy, and protect vital organs such as the kidneys and skeleton. Saturated fats derive primarily from animal sources; unsaturated fats from vegetable sources such as nuts and seeds. Vitamins are essential for normal growth, and are either fat-soluble or water-soluble. Fat-soluble vitamins include A, essential to the maintenance of mucous membranes, particularly the conjunctiva of the eyes; D, important to the absorption of calcium; E, an antioxidant; and K, which aids blood clotting. Water-soluble vitamins are the B complex, essential to metabolic reactions, and C, for maintaining connective tissue and cell functioning. Minerals are vital to normal development; calcium and iron are particularly important as they are required in relatively large amounts. Minerals required by the body in trace amounts include chromium, copper, fluoride, iodine, iron, magnesium,
manganese, molybdenum, phosphorus, potassium, selenium, sodium, and zinc.
Research Nutrition

ANIMAL CHEMISTRY

Animal Chemistry is the department of organic chemistry which investigates the composition of the fluids and the solids of animals, and the chemical action that takes place in animal bodies. There are four elements, sometimes distinctively named organic elements, which are invariably found in living bodies, that is carbon, hydrogen, oxygen, and nitrogen. To these may be added, as frequent constituents of the human body, sulphur, phosphorus, lime, sodium, potassium, chlorine, and iron.

The four organic elements are found in all the fluids and solids of the body. Sulphur occurs in blood and in many of the secretions. Phosphorus is also common, being found in nerves, in the teeth, and in fluids. Chlorine occurs almost universally throughout the body; lime is found in bone, in the teeth, and in the secretions; iron occurs in the blood, in urine, and in bile; and sodium, like chlorine, is of almost universal occurrence. Potassium occurs in muscles, in nerves, and in the blood-corpuscles. Minute quantities of copper, silicon, manganese, lead, and lithium are also found in the human body.

The compounds formed in the human organism are divisible into the organic and inorganic. The most frequent of the latter is water, of which two-thirds (by weight) of the body are composed. The organic compounds may, like the foods from which they are formed, be divided into the nitrogenous and non-nitrogenous. Of the former the chief are albumen (found in blood, lymph, and chyle), casein (found in milk), myosin (in muscle), gelatin (obtained from bone), and others. The non-nitrogeneous compounds are represented by organic acids, such as formic, acetic, butyric, stearic, etc by animal starches, sugars; and by fats and oils, as stearin and olein.
Research Animal Chemistry

BLACK WADD

Black wadd is an ore of manganese, used as a drying ingredient in paints.
Research Black Wadd

CHLORINE

Chlorine is a gaseous element with the symbol Cl.Chlorine was discovered by Scheele in 1774, who named it dephlogisticated marine acid. It was afterwards proved by Davy to be a simple body, and from its peculiar yellowish-green colour the appellation of chlorine (from the Greek chloros, yellowish-green) was given to it.

Chlorine occurs in nature in combination chiefly with sodium as common salt, from which it is liberated by the action of sulphuric acid and manganese dioxide. Chlorine is very active, uniting with more or less vigour with most elements to form chlorides. It unites quietly with hydrogen in dull light, and explosively in bright light or when the mixture is ignited.

Chlorine is a very heavy gas, being about two and a half times as heavy as ordinary air; it has a peculiar smell, and irritates the nostrils most violently when inhaled, as also the windpipe and lungs. It exercises a corrosive action upon organic tissues. It is not combustible, though it supports the combustion of many bodies, and, indeed, spontaneously burns several. In combination with other elements it forms chlorides, which act most important parts in many manufacturing processes. This gas may be liquefied by cold and pressure, when it becomes a transparent, greenish-yellow, limpid liquid. Chlorine is one of the most powerful bleaching agents, this property belonging to it through its strong affinity for hydrogen. Hence in the manufacture of bleaching-powder (chloride of lime) it is used in immense quantities. When applied to moistened coloured fabrics it acts by decomposing the moisture present, the oxygen of which then destroys the colouring matter of the cloth, etc. It is a valuable disinfectant where it can be conveniently applied, as in the form of chloride of lime.
Research Chlorine

DURALUMIN

Duralumin is an alloy of aluminium, copper and magnesium, with traces of other metals. Typically duralumin is comprised of 94.4 percent aluminium, 4.5 percent copper, 0.95 percent magnesium and 0. 76 percent manganese. If properly tempered it has an extremely high tensile strength and is used in aircraft construction.
Research Duralumin

GLASS

Glass is an artificial hard, brittle, transparent or translucent, noncrystalline solid, consisting of metal silicates or similar compounds fused with an alkali. In its finest qualities glass is quite transparent, and is used for making windows, mirrors, bottles, composite armour plate for armoured fighting vehicles etc.

The ancient Egyptians carried the art of making glass to great perfection, and are known to have practised it as early as 2000 BC, if not earlier. The Assyrians, the Phoenicians, the Greeks and Etruscans were all acquainted with the manufacture. The Romans attained peculiar excellence in glass-making, and among them it was applied to a great variety of purposes. Among the most beautiful specimens of their art are the vases adorned with engraved figures in relief; they were sometimes transparent, sometimes of different colours on a dark ground, and very delicately executed. The Portland or Barberini vase is almost the only surviving specimen of this kind. The mode of preparing glass was known long before it was thought of making windows of it. The first mention of this mode of using glass is to be found in
Lactantius, in the 3rd century AD. St Jerome also speaks of glass being so used in 422 AD.

Benedict Biscop introduced glass windows into Britain in 674 AD. In church windows it was used from the 3rd century. The Venetians were long celebrated for their glass manufacture, which was established before 700 AD. Britain did not become distinguished for glass until about the commencement of the 16th century.

The excise laws relative to the glass manufacture were at one time complicated in the extreme, and tended to check improvements in glass-making. These laws were repealed in 1845 by Sir Robert Peel, as part of his free-trade policy, and beneficial effects were immediately apparent in the improved quality, cheapness, and greater variety of descriptions of glass produced. Traditionally, glass is largely made in France, Germany, Belgium, and the United States. For coloured glass Bohemia has long had a high reputation.

The first mention of the manufacture of glass in the United States is in Captain John Smith's 'History of Virginia', in which he speaks of a glass factory having been founded at Jamestown in 1615, and a second in 1622. The work was coarse, being chiefly confined to bottles. In 1754, a successful factory was established in Brooklyn by Bamper, a Dutchman. In 1779, factories were founded at Temple, New Hampshire, and in 1795 the industry was begun at Pittsburgh. By 1813 there were five glass factories at Pittsburgh. In 1840 there were eighty-one factories in the United States, by 1870, 201 factories flourished in different places and since then the industry rapidly increased.

Glass is formed by the fusion of siliceous matter, such as powdered flint or fine sand, together with some alkali, alkaline earth, salt, or metallic oxide. The nature of the glass will depend upon the quality and proportion of the ingredients of which it is formed; and thus an infinite variety of kinds of glass may be made, but in commerce five kinds are usually recognized:

1. Bottle or coarse green glass. 2. Broad, spread, or sheet window-glass. 3. Crown-glass, or the best window-glass. 4. Plate-glass, or glass of pure soda. 5. Flint-glass, or glass of lead.

Coloured glass may be mentioned as a sixth kind. The physical properties of glass are of the highest importance. Perhaps the chief of these is its transparency, and next to that its resistance to acids (except hydrofluoric acid). It preserves its transparency in a considerable heat, and its expansibility is less than that of any other known solid. Its great ductility, when heated, is also a remarkable property. It can, in this state, be drawn into all shapes, and even be spun into the finest threads. It is a bad conductor of heat, and is very brittle. It is usually cut by the diamond.

The works in which glass is made are called glass-houses. They were traditionally constructed of brick, and made of conical form. A large vault was made in the interior of the cone, extending from side to side, and of sufficient height to allow workmen to wheel in and out rubbish from beneath the furnace, which was placed over the vault, and separated from it by an iron grating. The materials used for the formation of the glass are sometimes calcined in a calcar or fritting furnace, and a chemical union between the ingredients commenced, forming a frit. But this process is not essential, and the materials, after being ground and thoroughly mixed up together, are usually placed at once in melting pots or crucibles made of Stourbridge fire-clay, or other similar material, the melting-pots being then placed in the melting furnace or oven. This is a kind of reverberatory furnace, traditionally circular in form, arched or domed above, and capable of keeping up an intense heat. The crucibles are placed in the furnace at equal distances from each other round the circumference, each pot being opposite to an opening in the wall of the furnace in order that the crucible may be charged or discharged by the workman from without. In the 19th century a furnace called a tank furnace came into use which enabled melting pots to be dispensed with, as the material could be melted in and worked from the furnace directly.

The use of the annealing furnace, is also essential in glass-making, the process of allowing the glass to cool there being called annealing. Unless this process be carefully managed, the articles formed in the glass-house can be of no use, from their liability to break by the slightest scratch or change of temperature.

Sheet glass is the commonest description of glass. It is composed of various ingredients in varying proportions, usually of sand, chalk, or limestone, sulphate of soda, and cullet or broken glass. A coarse variety of it may be made of a mixture of two parts by measure of soap-boilers' waste, one of soda-ash and one of cleaned sand. In France the materials employed are commonly: sand 100 parts, sulphate of soda 30, carbonate of lime 30, coke to aid in the reduction of the sulphate of soda 5, with some bioxide of manganese to correct the greenish tinge that glass with a soda base possesses. Traditionally when the materials were properly melted a quantity was taken out of the pot on the end of an iron tube about 5 feet long, and the workman by blowing into and swinging the tube while heating and reheating the glass, imparted a cylindrical shape to the newly-formed product. The rounded extremity of the cylinder (which was about 4 feet long or more) was softened in the furnace in order to enable the workman to blow a hole in it. This opening was made by heating the cylinder and then stopping up the tube with the thumb, when the expansion of the air caused the cylinder to burst open at the end. The other rounded end was detached after cooling by winding round its circumference a thread of red hot glass, which caused a clear fracture. The cylinder was then split open parallel to its axis by a diamond, and then conveyed to the flattening furnace where it was heated and opened out into a flat sheet of glass. It was afterwards placed in the annealing furnace.

Crown glass is differently formed by different makers, but its composition is essentially the same as the best sheet glass. It used to be the only window-glass made in Britain, but its manufacture had been almost or altogether superseded by that of sheet glass by the start of the 20th century. The ingredients being melted and at the proper temperature, a quantity of the glass was withdrawn by the tube (to the amount, by successive addition, usually of 10 lbs in all). By various manipulations this from having the form of a hollow oblate spheroid was made to assume the form of a thin circular plate, with a thick part called the bull's eye in the centre, being the point at which an iron rod was attached to it for the purpose of causing it to revolve rapidly and spread out into a sheet before the furnace. The bull's eye used to be commonly seen in the windows of humble dwellings, the pieces of glass containing them being cheap.

Flint-glass or Crystal is one of the kinds largely made, being employed especially for table utensils, globes, ornaments, etc. Powdered flint was formerly employed in its manufacture, but fine white sand has been substituted. The other materials are red-lead or litharge, and pearl-ash (carbonate of potash). The following is said to be a good mixture : Fine white sand, 300 parts; red-lead or litharge, 200; refined pearl-ash, 86; nitre, 20; with a small quantity of arsenic and manganese. The furnace is kept at a very high temperature until the whole of the materials are fused. When the glass becomes translucent the temperature is diminished until it becomes a tenacious mass. Suppose a glass vessel is to be made, the iron tube is put into the crucible, and the required quantity of glass lifted out, which after certain adjustments is rolled into a cylindrical form on an iron table called the merver or marver. The workman
then blows the glass into the form of a hollow globe, and re-heats and blows until the globe becomes of the required thinness. An iron rod called the punty is now attached to the end of the glass furthest from the tube, and the tube detached. The workman now heats the glass on the punty, and sitting down upon a chair with smooth arms, he lays the punty upon them, and rolling it with his left hand he gives the glass a rotatory motion, while with an instrument in his right, somewhat like a pair of sugar-tongs, he enlarges or contracts the different parts of the vessel until it assumes the requisite shape. A pair of shear's is al.so made use of in certain cases. The article is then detached from the punty, and carried to the annealing furnace. Many of the articles, after coming from the annealing furnace, are sent to the cutter or grinder. The operation of grinding is performed by wheels of various diameter and of various edges, some of iron, others of stone, and some of wood. Rich and delicate designs may be cut upon the articles by means of small wheels of copper and steel upon which emery is kept constantly falling.

Ornamental figures may also be engraved, or rather etched, upon articles of glass by means of hydrofluoric acid, care being taken to place a coating of some substance over the parts not to be acted upon. Various ornamental forms are given to the surface of glass vessels by metallic moulds. The mould is usually of copper, with the figure cut on its inside, and opens with hinges to permit the glass to be taken out. The angles of moulded objects are always less sharp than those of cut-glass.

Green or bottle-glass is formed of the coarsest materials, such as coarse sea or river sand, lime, and clay, and the most inferior alkalies, as soap-boilers' waste, and the slag of iron ore. A cheap mixture for this kind of glass may be made of common sand and lime, with a little clay and sea salt. The manipulations of the traditional glass-blower in fashioning bottle-glass into various forms were in general the same as those performed by the flint-glass blower. Wine and beer bottles, which are required to be all of a certain capacity, are blown in moulds, so that their containing portion may be as nearly as possible of the requisite size. When the articles are made they are carried to the annealing furnace. Green bottle-glass is preferable to all other kinds for vessels required to contain corrosive substances; it is less fusible than flint glass, and
thus is better calculated for many chemical purposes.

Plate-glass is a fine and thick glass cast in sheets. One maker's ingredients are as follows: white sand, 300 lbs; soda, 200; lime, 30; oxide of manganese, 2; oxide of cobalt, 3 ounces; and fragments of glass (cullet) equal to the weight of sand. After being melted in large crucibles, and the liquid glass having been thoroughly skimmed, it is transferred by a copper ladle to smaller pots (cuvettes). When the glass in the smaller crucible is ready for casting it is poured upon an iron casting-table, and a large metal cylinder moved along spreads the glass into a broad uniform sheet. The subsequent stages of the process are concerned with the discovery of flaws, the squaring of the edges, the grinding of the surfaces plane, the grinding of the sides, and the polishing. Before grinding and polishing the glass is what is called common 'rough plate,' and in this state it is much used for roofing, cellar-lighting, etc, being non-transparent. 'Rolled plate,' which is cast on a table that imparts a surface of grooves, flutings, lines, etc, is extensively used for the same purposes.

There are several other kinds of glass that may be noticed. Pressed glass is flint-glass formed into articles by pressing into moulds of iron or bronze, a fine surface being afterwards attained by heating so that a thin film on the surface melts.

Slag glass is glass from the slag of blast-furnaces mixed with other ingredients; it is largely used for bottles.

Optical glass is made of special varieties of flint and crown glass.

Strass, which was used for imitating gems, was a very dense flint-glass, colours being imparted by metallic oxides.

Spun glass is glass in the form of very fine threads, in which state it may be woven into textile fabrics of great beauty.

Toughened or hardened glass, having certain properties owing to its being heated to the melting point and plunged into an oleaginous mixture, was invented prior to the start of the 20th century, but was not developed into a working product until the mid-20th century, and is now very commonly used for windows.

Coloured glass is of two kinds - entirely coloured, the colouring matter being melted along with the other ingredients; or partially coloured, a quantity of white glass being gathered from one pot, and dipped into the other containing the coloured glass, by which the whole receives a skin of coloured glass. The colouring matters are chiefly the metallic oxides. A beautiful yellow colour is imparted by silver in union with alumina (powdered clay and chloride of silver being used), also by uranium and by glass of antimony; red colours by oxide of iron, copper, and gold; green by protoxide of iron, oxide of copper, oxide of chromium, &c.; blue by cobalt; orange by peroxide of iron with chloride of silver. ohemia is particularly famous for its manufactures of articles in coloured glass.
Research Glass

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