Artesian Wells, so called from the French province of Artois, where they appear to have been first used on an extensive scale, are perpendicular borings into the ground through which water rises to the surface of the soil, producing a constant flow or stream, the ultimate sources of supply being higher than the mouth of the boring, and the water thus rising by the well-known law. They are generally sunk in valley plains and districts where the lower pervious strata are bent into basin-shaped curves.
The rain falling on the outcrops of these saturates the whole porous bed, so that when the bore reaches it the water by hydraulic pressure rushes up towards the level of the highest portion of the strata. The supply is sometimes so abundant as to be used extensively as a moving power, and in arid regions for fertilizing the ground, to which purpose artesian springs have been applied from a very remote period. Thus many artesian wells have been sunk in the Algerian Sahara which have proved an immense boon to the district.
The water of most of these is potable, but a few are a little saline, though not to such an extent as to influence vegetation. The hollows in which London and Paris lie are both perforated in many places by borings of this nature. At London they were first sunk only to the sand B B, but latterly into the chalk c o. One of the most celebrated artesian wells is that of Crenelle near Paris, 1798 feet deep, completed in 1841, after eight years' work. Artesian wells are now common in many countries, and have been sunk to the depth of a mile or more. As the temperature of water from great depths is invariably higher than that at the surface, artesian wells have been made to supply warm water for heating manufactories, greenhouses, hospitals, fish-ponds, etc. Petroleumwells are generally of the same technical description. Artesian wells were later made with larger diameters than formerly, and altogether their construction was rendered much more easy after the industrial revolution. Research Artesian Wells
Dyeing is the art of giving colour to textile and other articles in such a way that the colours are more or less permanent, and not readily affected by the action of light, washing, etc. Like spinning and weaving it was originally a home industry, as it still is in many places. Until about 1850 natural dye-stuffs alone were employed, but the discovery of dyes of all colours that can be obtained from coal-tar products revolutionized dyeing as an industry, and the vegetable dye-stuffs were gradually superseded by the newer colours.
Before dyeing, the materials have generally to be cleansed or bleached to get rid of undesirable colouring matters or impurities; and frequently a textile material is subjected to some subsidiary treatment in order to obtain special effects. For example, cottonyarn may be subjected to the action of strong causticsoda ('mercerizing' process) while in a state of great tension, in order to give it a permanent silky lustre.
Dyeing is not only an art, it is also a branch of applied chemistry. One fundamental principle is, that the colouring matter and other necessary substances must be applied in a state of solution, and while in direct contact with the fibre they must be rendered insoluble, so that they are precipitated within or upon the fibre and thus permanently fixed. The method of effecting this varies greatly according to the fibre and the colouring matter employed. As a rule the vegetable and the animal fibres are dyed by very different methods. The affinity of the animal fibres for certain colouring matters is often so great that they are readily dyed by simple immersion in hot colour solutions;
but this simple process is not generally sufficient. According to the method of their application in dyeing the following groups: of dye-stuffs may be distinguished: Avid Colours, Basic Colours, Direct Colours, Developed Colours, Mordant Colours, Miscellaneous Colours, Reactive Colours.
The acid colours are so called because they are of an acid character and are applied in an acid dye-bath. As a rule, they are only suitable for dyeing the animal fibres, e.g. wool and silk, also leather, horn, feathers, etc. Only a few vegetable dye-stuffs belong to this class, for example, the purple colour orchil and the blue colour indigo extract. On the other hand, the acid colours derived from coal-tar - and increasingly petroleum - are very numerous and yield a great variety of hues - red, orange, yellow, green, blue, violet, brown, and black, each with its particular name.
The basic colours are so called because their essential constituents, to which they owe their dyeing power, are organicbases. The bases themselves are colourless and too insoluble in water to be of use, hence they are employed in the form of their soluble coloured salts, usually the hydrochlorides of the colour-bases. Their solutions are precipitated by tannic acid, because it combines with the colour-bases to form insoluble tannates. Wool, silk, and animal substances generally have a direct attraction for colour-bases, and hence these fibres are readily dyed by simple immersion in hot aqueous solutions of the basic colours. Cotton and linen, on the other hand, are not dyed so readily; they need first to be prepared or impregnated with tannic acid, and thus prepared are said to be mordanted, the tannic acid in this connection being styled the mordant. Most of the colours of this class are fugitive to light, and all but one, barberryroot, are derived from coal-tar products.
The direct colours are so called because they dyecotton direct, that is, without the aid of any mordanting process. The first of this class derived from coal-tar was congo red, discovered in 1884; this group includes a very great variety of fast colours, and forms, indeed, one of the most important and valuable series of dye-stuffs employed. Cotton, linen, and the vegetable fibres generally are dyed in the simplest possible manner by merely boiling them in a solution of the dye-stuff, with or without the addition of a little soap, carbonate or sulphate of soda, etc. Wool and silk are frequently dyed in the same manner as cotton. Very few vegetable dye-stuffs belong to the direct colours, e.g. Safflower, Turmeric, Saffron, Annatto. They are all fugitive, and have been of little or no importance to the dyer since the end of the 19th century. The coal-tar colours of this class, on the other hand, are extremely numerous.
The developed colours include a variety of colours which are formed in situ upon the fibre by the successive application of two or more substances. These colours are all of coal-tar origin. A number of them belong to the so-called azo colours, derived from compounds containing nitrogen.
The mordant colours form one of the most important classes of colouring matters, for they include not only most of the vegetable dye-stuffs, e.g. madder, logwood, fustic, etc, but also many valuable fast coal-tar colours, commonly known as the alizarin colours, after their typical representative, alizarin. These mordant colours have by themselves very little colouring power, as a rule, and if employed alone in dyeing give little or no result. If applied, however, in conjunction with metallic salts, notably those of chromium, aluminium, iron, tin, and copper, they each yield a variety of colours, according to the metallic salt employed. In employing them usually two distinct operations are involved: first, that of applying the metallic salt or mordant, called the mordanting process ; and second, that of dyeing proper, in which the mordanted material is boiled in a solution or decoction of the dye-stuff. During the dyeing operation the colouring principle of the dye-stuff combines with the metallic salt already upon the material, and the colour is thus produced and fixed upon the fibre. The method of mordanting varies with the fibre and the metallic salt employed. The vegetable dye-stuffs of this class include Madder, Sapanwood, Camwood, Barwood, Old Fustic, Young Fustic, Quercitron Bark, Persian Berries, Weld, Logwood. Madder was formerly the most important and highly valued of the dye-stuffs of this class, being especially employed to produce the fine 'Turkey-red' dye; but was entirely superseded by the coal-tar colour alizarin towards the end of the 19th century.
Reactive colours combine directly with the fibre being dyed through a chemical reaction and result in a fast colour. The first ranges of reactive dyes for cellulose fibres were introduced in the mid-1950s.
Similarly, the employment of cochineal (an insect dye) has also greatly diminished through the introduction of the cheaper colours. Camwood and barwood are almost entirely used in wool-dyeing, either in conjunction with the indigo-vat or for the purpose of dyeing various shades of brown. Old fustic is the most important of the yellow mordant dye-stuffs, and the colours are fast although not very brilliant. Young fustic yields fugitive colours, and has been little used since 1900. Quercitron bark is an excellent dye-stuff employed by wool-dyers for the production of bright orange and yellow colours. Persian berries and weld, a species of wild mignonette, are both excellent dye-stuffs, but their employment is now limited. Logwood is largely employed by wool, silk, and cotton dyers for dyeing black and dark-blues, which, although fast to washing, are only moderately so towards light. During the 20th century dyewoods were gradually replaced by coal-tar colours.
Among miscellaneous colours are several dye-stuffs applied in a distinct manner. Indigo is a dark-blue powder quite insoluble in water, but can be rendered soluble for dyeing purposes by two methods. The first method converts the indigo into so-called indigo extract, which is sold as a blue paste and applied as an acid colour in dyeing wool and silk. In the second method the indigo-blue is converted into indigo-white, which readily dissolves in the alkalipresent, the solution thus obtained being called an indigo-vat. If cotton, wool, or silk is steeped for some time in the clear yellow solution of such a vat, and then exposed to the oxidizing influence of the air, they are dyed a permanent blue. The indigo-white absorbed by the fibre loses its acquired hydrogen, and thus insoluble indigo-blue is regenerated within and upon the fibre. Aniline black is a valuable colour, produced direct upon the fibre by the oxidation of aniline, and remarkable for its extreme permanency.
Catechu is a vegetable dye-stuff used in dyeing cotton and woollen brown. On wool, catechu yields khaki browns in single bath by using copper sulphate as the mordant. On silk it is largely employed for weighting purposes in the process of dyeing black. Chrome Yellow, Iron Buff, Prussian Blue, and Manganese Brown, employed in cotton dyeing, are frequently classed as mineral colours. Chrome yellow is obtained by immersing cotton successively in solutions of acetate of lead and bichromate of potash, whereby the yellow precipitate of chromate of lead is fixed upon the fibre. Iron buff is obtained in a similar manner by the successive application of iron sulphate and carbonate of soda, and finally developing the full colour by washing with water and exposure to air. The buff colour is really due to the precipitation of oxide of iron on the cotton. Prussian blue is at once developed by passing the buff-dyed cotton through an acidified solution of potassium ferrocyanide. The production of manganese brown on cotton is similar to that of iron buff. The brown colour ultimately produced upon the fibre is an oxide of manganese. The mineral colours are very useful for certain purposes, and are to be regarded as very fast to light. Research Dyeing
Westrumite was a road-dust preventing material composed primarily of petroleum and ammonia. It was developed around 1900 in response to the spread of motoring and the dust raised by cars using the roads. Research Westrumite
Fritz Haber was a German chemist. He was born in 1868 and died in 1934. His conversion of atmospheric nitrogen to ammonia opened the way for the synthetic fertilizer industry. His study of the combustion of hydrocarbons led to the commercial cracking or fractional distillation of natural oil (petroleum) into its components (for example, diesel, gasoline, and paraffin) . In electrochemistry, he was the first to demonstrate that oxidation and reduction take place at the electrodes; from this he developed a general electrochemical theory. At the outbreak of war, the German Army asked the Institute to investigate substitutes for explosive in shells, and poison gas was suggested. Haber, after watching early trials with gas shells, proposed releasing gas from cylinders. He became one of the principals in the German chemical warfare effort, devising weapons and gas masks, leading to protests against his Nobel Prize, awarded in 1918. Research Fritz Haber
Gottlieb Daimler was a German engineer. He was born in 1834 at Schorndorf, Wurtemberg and died in 1900. After arriving in England he was employed at the Whitworth works at Manchester. Returning to Germany with Dr Otto of Cologne he perfected the Otto gas engine. From 1882 he devoted himself to experimenting with high power gas and oil engines, and petroleum motors. Research Gottlieb Daimler
Colostomy is the operation of opening into the colon, or lower portion of the intestine. This procedure is one of the most important in abdominal surgery. It is sometimes necessary as a life- saving measure. It may be temporary or permanent as an artificial anus in the radical treatment of rectal cancer. Because of its appearance, its inconvenience and the very thought of an artificial opening in the abdominal wall a great deal of care is necessary to allay the anxieties of patients and their relatives when colostomy is necessary.
In some cases of acute intestinal obstruction the surgeon explores the abdomen and finds perhaps a large mass in the region of the pelvic colon or rectum that cannot be removed. An emergency colostomy is then performed in the transverse colon with the immediate purpose of saving life and with the further objective of providing temporary drainage should the growth be removable at a later date. In some such cases, when at first sight the primary cause of the obstruction seems beyond any possibility of surgical removal, after several weeks of colostomy drainage the infection subsides and the affected portion of bowel may then be removed. Colostomy may be necessary as a preliminary to other operations involving removal of the large bowel. Such an occasion arises if diverticulitis has produced vesico-colic fistula (between the colon and bladder). In some cases of severe incontinence due to abnormality or injury to the anus, a left iliac colostomy enables the patient to be free of the terrible inconvenience of perpetual soiling in the perineum. Injuries or abnormalities of the spinal cord produce paralysis of the anal sphincter mechanism and sometimes colostomy is essential. Congenital absence of the rectum or anus requires an emergency colostomy within a day or so of birth.
There are two main forms of colostomy. First is the loop colostomy which has two limbs. The opening is at the apex of the loop and the bowel has not been divided completely across. A variation of the loop colostomy is the double- barrel form in which the two limbs of the loop are separated by a piece of skinrafter complete division. This is also described as a defunctioning colostomy as it prevents the spill of faeces from the proximal to the distalloop. A second variety is the spur colostomy where a spur is formed by suturing the two ends together for several centimeters inside the abdomen. This is of particular value if the colostomy is temporary as the spur can be destroyed by a crushing clamp without risk of peritonitis or perforation since the limbs have become sealed together. When the spur breaks down, the artificial opening on the surface shrinks and sinks back below the skin level. The aim is that this should close spontaneously without further operation. The third type is the terminal colostomy in which the distal portion of bowel is removed completely or in the case of excision of rectum the lower end is closed to form a blind end. In grave emergencies the simplest form of colostomy is performed in which a loop of colon is brought out through the abdominal wall, where it is held by the insertion of a glassrod passed through a small hole in the mesentery. The ends of the glassrod are connected by a loop of rubber tubing which forms a 'bucket handle' . The abdominal wall is closed around the protrusion of the colostomy. Exteriorisation is another way of performing a colostomy. If a growth is present in a part of the bowel which can be brought readily through the abdominal wall (e.g. transverse or pelvic colon) the affected loop containing the growth is left outside and the peritoneum, muscles and skin are closed around the base of the loop where the two limbs converge. The loop of colon containing the growth is then removed, leaving two open ends of el which can later be joined by crushing the spur between them. This operation avoids the handling of growth or unprepared bowel while the peritoneal cavity is open and so diminishes the risk of peritonitis. A formal operation for closure is required if a spur has not been made.
At the end of the operation a small incision is usually made in the apex of the loop to allow the immediate discharge of gas and faecal material which is collected as cleanly as possible before the patient leaves the theatre. A dressing of petroleum jelly gauze or tullegras is applied on the exposed bowel. The skin incision may be sealed with Whitehead's varnish and a pad of cellulosetissue and wool is bandaged lightly over the opening. For fear of contaminating the abdominal wound before the peritoneal cavity has become sealed, the former practice was to leave the colostomy unopened for 48 hours. The initial opening may be enlarged by the surgeon two or three days after the colostomy has been raised. The bowel is usually divided (without anaesthetic) by an electric cautery which seals the blood vessels and prevents bleeding from the very vascular mucousmembrane and muscle wall of the bowel. A method of draining the colostomy is by the use of Paul's tube. This is an angled wide glass tube which is inserted through a hole in the colostomy loop. It is tied in position in the same way as the caecostomy catheter and connected to a bedside jar with wide, thin, latex tubing. Research Colostomy
Benzene, benzine or benzol is a a liquid hydrocarbon obtained from coal-tar or distillate of petroleum obtained from benzol by treating it with sulphuric acid and then distilling, used as a solvent in dry cleaning and painting. Benzene was discovered by Faraday in the oils of portable gas in 1825 and obtained by Mitscherlich from benzoic acid in 1834, and by Mansfield from coal tar in 1848 (he also died as the result of burns sustained while experimenting with benzene). It has the formulae CgHg and is quite colourless, of a peculiar agreeable odour and is used by manufacturers of india-rubber and gutta-percha, on account of its great solvent powers, in the preparation of varnishes, also for removing grease from fabrics, gloves, etc. It is the parent substance for most of the aniline dyes and for other substances, e.g. saccharin. It is inflammable, burning with a very smoky flame. Research Benzene
Carbon is a non-metallic, chiefly trivalent element found native (as in diamond and graphite) or as a constituent of coal, petroleum, and asphalt, of limestone and other bicarbonates, and of organic compounds or obtained artificially in varying degrees of purity especially as carbon black, lampblack, activated charcoal and coke. It has the symbol C and is contained in all life forms.
The diamond is the purest form of carbon; in the different varieties of charcoal, in coal, anthracite, etc, it is more or less mixed with other substances. Pure charcoal is a black, brittle, light, and inodorous substance. It is usually the remains of some vegetable body from which all the volatile matter has been expelled by heat; but it may be obtained from most organic matters, animal as well as vegetable, by ignition in close vessels. Carbon, being one of those elements which exist in various distinct forms, is an example of what is called allotropy. The compounds of this element are more numerous than those of all the other elements taken together. With hydrogen especially it forms a very large number of compounds, called hydrocarbons, some of which have latterly become of the greatest economic importance. With oxygen carbon forms only two compounds, but union between the two elements is easily effected. Research Carbon
Abbreviations
Research Artesian Wells
